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Mechanisms of Polymerization Reactions

Lecture Excercise/laboratory
2019, Winter Semester
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Credits 4
Hours per week 2 / 1 / 0
Examination C+Ex
Study Language Czech
Level []
Guarantor prof. Ing. Petr Sysel, CSc.

Summary

Mechanisms of step and chain (radical, ionic, stereospecific)polymerizations, copolymerizations and polymer reactions are lectured. Evaluations of the selected kinetic and thermodynamic experimental data of polymerizations are practised. Prerequisities: macromolecular chemistry. Instructions concerning the examination are provided at the Department of Polymers.

Syllabus

1. Introduction. Nomenclature of polymer. Classification of polymerization reactions.
2. Step-growth polymerizations.
3. Special polymers.
4. Chain-growth polymerizations.
5. Mechanisms of radical polymerizations.
6. Mechanisms of ionic and stereospecific polymerizations.
7. Living and controlled polymerizations.
8. Copolymerization.
9. Polymerization of cyclic monomers.
10. Inorganic polymers.
11. Reactions of polymers.
12. Evaluation of the selected kinetic experimental data of polymerizations.
13. Evaluation of the selected thermodynamic experimental data of polymerizations.
14. Trends in macromolecular chemistry.

Literature

A:Encyclopedia of Polymer Science and Technology, J. Wiley @ Sons (http://www.vscht.cz/pol/)

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