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Chemistry of Inorganic Materials I

Credits 4
Hours per week 2 / 1 / 0
Examination C+Ex
Study Language Czech
Level Master subject
Guarantor doc. Dr. Ing. Martin Havlík Míka

Summary

The subject is focused on chemical and physical processes that are important for the preparation of new materials with precisely targeted properties. The approach is based on the thermodynamics of phase equilibrium in condensed systems. Substantial attention is paid to chemical equilibrium, reactivity and stability of materials. The subject also involves the thermodynamics of sintering, the precipitation of new phases and the properties of dispersed systems. Examples are presented describing the development and preparation of new advanced materials.

Syllabus

1. Basic characterization of non-metallic materials.
2. High-temperature phase equilibria in one-component systems.
3. Phase diagrams and equilibrium pressures of important compounds.
4. High-temperature phase diagrams of binary systems.
5. High-temperature phase diagrams of ternary systems.
6. Construction of phase diagrams.
7. Chemical reaction equilibrium of pure condensed phases.
8. Chemical reaction equilibrium in solid and liquid solutions.
9. Reactivity and stability of glass and ceramic materials.
10. Thermodynamic data - tabulation, standard states.
11. Phase equilibrium on curved surfaces.
12. Dispersed systems and their properties.
13. Precipitation of a new phase by nucleation and spinodal decomposition.
14. Thermodynamics of sintering.

Literature

R:Šatava V., Rybaříková L., Matoušek J.: Fyzikální chemie silikátů I, SNTL, 1986.
R:Moore W.: Fyzikální chemie, SNTL, 1981, ISBN: 10421852.
A:Šatava V.: Úvod do fyzikální chemie silikátů, SNTL, 1965, ISBN: 0483565.
A:Atkins P., De Paula J.: Atkins’ Physical Chemistry, Oxford University Press, 2002,ISBN: 0198792859.
A:Babushkin V.I., Matveyev G.M., Mchedlov-Petrossyan O.P.: Thermodynamics of Silicates, Springer, 1985,ISBN: 038712750X.

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